The modbus id goes in UnitId in module.
If you let the PLC control de R/W (Process=1 and specify PLC thread), then in each scan cycle the PLC will use the module properties to send a commands to all modules it controls. In the example case, the PLC will send one command to slave id = 1, command code = 03 (read holding registers), address = 0x0000 (default 40001). For Continous=1 R/W is automatic.
If you need manual control of read/write cyle, which is somewhat disarable for slow connections, you need to set Continous=0, and use the SendOp flag from PLC or application.
C.